Aniline synthesis by amination (arylation) - Organic Chemistry …
Various anilines are prepared by treatment of functionalized arylboronic acids with H 2 N-OSO 3 H (HSA) as a common, inexpensive source of electrophilic nitrogen, under basic aqueous …
Direct and Practical Synthesis of Primary Anilines through Iron ...
2016年10月31日 · Herein, we report an operationally simple arene C–H amination reaction that, in contrast to most literature precedent, affords directly the synthetically versatile primary aniline …
Halogenation of Anilines: Formation of Haloacetonitriles and …
2024年9月19日 · The trihalomethane yields of anilines correlated with their haloacetonitrile yields. Product analysis of aniline chlorination by liquid chromatography–high-resolution mass …
Synthesis, Characterization, and Structures of a Persistent Aniline ...
2012年10月18日 · Feeling the heat: The aniline radical cation TBA.+ (TBA=2,4,6- t Bu 3 C 6 H 2 NH 2) has been successfully stabilized both in solution and in the solid state. It exists as two …
Chapter 3: Synthetic Methods for Primary Anilines - books.rsc.org
2023年12月15日 · In N -arylation reactions, several types of organic electrophile coupling partners such as (pseudo)halides (Ullmann-type and Buchwald–Hartwig couplings) and boronic acids …
Synthesis of Anilines - Hartwig - Major ... - Wiley Online Library
Competing formation of N - and C (3)-arylation products has been observed when coupling indole and pyrrole with aryl bromides containing ortho -substituents. These hindered aryl halides do, …
An overview of Aniline-Based Schiff base metal Complexes: …
2024年1月1日 · The synthesis pathways involving aniline-based Schiff base ligands and their subsequent coordination with diverse metal ions are critically analyzed, emphasizing the …
para -Selective C–H Olefination of Aniline Derivatives via Pd/S,O ...
2019年3月28日 · Herein, we report a highly efficient para -selective C–H olefination of aniline derivatives promoted by a Pd/S,O-ligand based catalyst (Scheme 1 d). The reaction proceeds …
From alkylarenes to anilines via site-directed carbon–carbon ... - Nature
2018年10月29日 · Here we report a previously elusive C–C amination protocol for aniline synthesis from simple and readily available alkylarenes or substituted benzyl alcohols to …
Anilines Formation via Molybdenum‐Catalyzed Intermolecular …
2024年9月10日 · Here, we report an unprecedented and efficient approach for the synthesis of 2,4-di and 2,4,6-trisubstituted anilines. With a simple molybdenum (VI) catalyst, a wide range …